Quote

“It may not be amiss to give a general idea of the method that has enabled us to arrive at results, remarkable in their simplicity and generality, which it would be very hard if not impossible to demonstrate in the ordinary way.”

— George Green (1828)

Motivation

Poisson’s equation,

can be solved by direct Coulomb integration when is completely specified. However, in many physically important situations — conducting boundaries, dielectric interfaces, or mobile charges that redistribute in response to the field — some portion of is unknown and must be determined self-consistently. This is the boundary value problem: given the free (volume) charge and conditions on surfaces, find the total potential.

The volume part of is typically specified (external charges we control), while the surface part (induced charges on conductors, polarization charges on dielectrics) is determined by the solution itself. Thus, the task is to find the field produced by charge induced on nearby conductors and/or simple dielectrics.

Strategy: Superposition

Write as a sum of a particular solution of Poisson’s equation (accounting for the known charge) and a general solution of Laplace’s equation (chosen so the total satisfies boundary conditions). This works because solutions to Laplace’s equation form a complete set that can represent any function needed to enforce boundary conditions on .

For a charge fixed at in a volume with specified on :

Solutions for “nice” geometries (obtained via the method of images) are useful because they can be superposed for more complex configurations — this idea is generalized in the Green function method.


Method of Images

The method of images can directly attack Poisson’s equation systems in which a planar, spherical, or cylindrical boundary separates space into a volume and its complement . Given charges in , we place fictitious image charges in that simulate the effect of the actual induced charge distribution on the boundary.

Rules of the Method

  1. Image charges must lie outside the physical volume — never inside it.
  2. Image charges must produce a potential that satisfies Laplace’s equation in (they are sources only in ).
  3. The combination (real + image) must satisfy the boundary conditions on .
  4. The method provides information about the potential only in — not in .
  5. By uniqueness, the solution so obtained is the solution.

Point Charge and a Grounded Conducting Plane

Charge at height above an infinite grounded plane at . Place image at :

The first term is the particular solution of PE in ; the second solves LE in and enforces .

The induced surface charge density is:

which integrates to — every field line leaving terminates on the plane.

Image Energy Is Half the Naïve Answer

The interaction energy is not in the potential of its image — it is half of that. The image charge is not an independent source; it tracks as moves. Always integrate the force, or use over the physical half-space only. Same trap appears for image charges with spheres, cylinders, and dielectric interfaces.

Planar Dielectric Interface

Charge at in a medium with ; the half-space has .

Image system: To find in : fill all space with , place at original position plus image at . To find in : fill all space with , place image at .

The “fill all space” trick works because in a uniform medium, the potential of a point charge is simply Coulomb divided by the permittivity — matching boundary conditions then fixes the image charges. Uniqueness guarantees the result.

The force on (from the field of alone):

which matches the result found in Chapter 6 via direct calculation of . The stress tensor confirms this is the negative of the force on the interface.

Limits

  • : , recovering the grounded conductor result. Field lines are perpendicular to the interface.
  • : , no interface effects.

TODO: Add picture of field lines.

Multiple Images: Parallel Conducting Planes

Charge midway between two grounded planes at and . Placing at and to satisfy each plane individually violates the other’s boundary condition. An infinite sequence of images is required: positive charges at and negative charges at for all integers .

Spherical Boundary: Grounded Sphere

Charge at distance from the center of a grounded conducting sphere of radius (with ). By symmetry, the image lies on the line connecting to the center (choose as axis). Evaluating at and :

Since is the geometric mean of and , the image lies inside the sphere. The potential for :

Since , not all field lines terminate on the sphere — some escape to infinity (unlike the conducting plane, where the infinite surface captures all lines).

The force on the sphere:

This force is always attractive and falls off as for (compared to for the plane). The asymptotic difference reflects the geometry: the plane subtends a full half-space of solid angle regardless of distance, while the sphere’s solid angle shrinks as , so its ability to “intercept” field lines diminishes with distance.

Generalizations: Fixed Potential and Net Charge

Sphere at fixed potential : Add a charge at the center to raise the boundary potential uniformly:

Sphere with net charge : Add at the center to cancel the image, plus at the center to set the total charge:

Line Charge and Conducting Cylinder

Infinite line charge at distance from the axis of a conducting cylinder of radius (with ). Guess image at position inside the cylinder:

For closed, bounded equipotentials to exist, the logarithmic divergence must cancel at large distances: . The equipotential condition on the cylinder surface then gives:

Same inverse-point relation as the sphere, but now all field lines terminate on the cylinder (, unlike the sphere where ).

Dielectric Cylinder

Line charge at distance inside a cylinder of radius with , embedded in .

Interior (): Fill all space with , place source plus image at the inverse point .

Exterior (): Fill all space with , place image at the source position plus compensating at the origin (net neutrality of the cylinder).

Matching both and at the boundary:

These are identical to the planar dielectric interface ratios — a consequence of the conformal map that unrolls the cylinder into a plane.


The Green Function Method

To solve PE for with boundary conditions on , introduce a Green function satisfying PE for the same volume with a point source:

Applying Green’s second identity with and :

This integral equation involves both and on . The art is to choose boundary conditions for that eliminate one, making the formula explicit.

The Dirichlet Green Function

Set for . The third integral vanishes:

Physical interpretation: is the potential at due to a unit point charge at , with acting as a grounded conductor ( vanishes there).

Reciprocity: Using Green’s second identity with and , integrating over :

This symmetry is immensely important: it transforms the formula above into the magic rule:

Now is computed as the potential at for a source at : we need only calculate one Green function for a given volume, and can then find for arbitrary and .

Free-space Green function ( at infinity): .

Interior vs. exterior: For a finite grounded surface, one can define two Green functions — interior () and exterior (). Reciprocity applies to each separately.

The Neumann Green Function

We cannot naively set on because integrating the defining PE over gives . Instead:

where is the area of . Then:

Neumann conditions do not arise naturally in electrostatics with stationary charge. Although relates the normal derivative to conductor surface charge, is determined by the solution, not prescribed in advance. Neumann conditions do appear in steady-current problems and waveguide theory.

Mixed boundary conditions (e.g., a conducting shell occupying only part of , or finite-sized capacitor plates) require more exotic mathematical methods (Sneddon 1966, Fabrikant 1991).


Computing the Dirichlet Green Function

For planar, cylindrical, and spherical boundaries, the method of images directly gives . For other geometries, we present three systematic methods.

Method I: Eigenfunction Expansion

Find eigenfunctions of the Laplacian satisfying homogeneous Dirichlet conditions:

By Sturm–Liouville theory, the operator with these BCs is self-adjoint (not the same as Hermitian in general). This guarantees a complete orthonormal set: . The Green function is:

This satisfies the PE (apply the eigenvalue equation) and the BC ( for each term). Finite domains give discrete modes; infinite domains give continuous spectra (plane waves in Cartesian, Bessel functions in cylindrical, etc.).

Method II: Direct Integration

Algorithm:

  1. Represent as a product of 1D deltas; use completeness relations for all but one coordinate.
  2. Motivate an ansatz for that reduces the 3D PE to an inhomogeneous ODE in the remaining coordinate.
  3. Solve the ODE with continuity of and a jump condition on at the source point (from integrating the delta).

Method III: Splitting

Decompose , where satisfies LE in and is chosen so on . This works when is known in the relevant coordinate system.


Complex Potential Methods

The basic machinery — analytic , conformal maps, equipotentials and field lines as level curves — is developed in Chapter 7. Here we apply it to systems with explicit line sources, where the logarithmic singularity of encodes the line charge.

For 2D problems (line charges), the potential is the real part of an function:

analytic everywhere except . Superposition builds arbitrary 2D charge distributions.

Line dipole: Taking , with finite:


The Poisson–Boltzmann Equation

So far, volume charge has been specified and immobile. When mobile charges redistribute in response to the field, is itself determined by .

Model: Plane with fixed charge density , embedded in a medium () containing mobile particles (charge , number density ) obeying Boltzmann statistics: .

The Poisson–Boltzmann equation:

Algebraic vs. Exponential Screening

Mobile charges screen the field of the charged interface algebraically (). Compare with Thomas–Fermi screening, where a neutral medium of mobile + immobile charges screens a point charge exponentially (). The difference: here the mobile charges alone must neutralize — there is no background of fixed opposite charge to set a screening length. The characteristic scale is set by the geometry (surface charge density) rather than by a bulk property.

Applications: Colloidal suspensions, biological membranes, semiconductor interfaces (Gouy–Chapman theory), and electrochemistry all involve the Poisson–Boltzmann equation. The nonlinear version is essential when .


Problems

Method of Images

8.1 — The Image Force and Its Limits

A grounded conductor of arbitrary shape has characteristic size . A point charge is at distance . Show the force varies as .

8.2 — Point Charge near a Corner

Two grounded semi-infinite conducting planes meet at a right angle. Find the charge induced on each plane when is introduced at angle from one plane.

8.4 — A Dielectric Slab Intervenes

Dielectric slab (, thickness ) between and . Point charge at origin. With , show:

8.5 — Force on a Dielectric Interface

Point charge at in ; half-space has .

  • (a) Show stress tensor gives force on interface equal and opposite to .
  • (b) Show Coulomb force on gives the wrong answer.

8.7 — Images in Spheres I

Charge at from center of an isolated conducting sphere (radius ); force is zero there. Move to ; show force is repulsive with .

8.9 — Debye’s Model for the Work Function

Conducting sphere of radius ; image force becomes operative at distance outside.

  • (a) Find .
  • (b) Take .

8.10 — Line Charge and Conducting Cylinder

Line charge at perpendicular distance from axis of cylinder .

8.11 — Point Dipole in a Grounded Shell

Dipole at center of grounded sphere of radius . Show .

8.12 — Inversion in a Cylinder

Green Functions

8.14 — Green Function Inequalities

8.15 — Potential of a Voltage Patch

Grounded plane except for area at potential . Show:

8.17 — Free-Space Green Functions by Eigenfunction Expansion

Find in dimensions.

8.19 — Cube Green Function

Interior Dirichlet Green function for cube . Find on face for at center.

8.22 — Green Function for a Dented Beer Can

Cylinder of radius , height , with a wedge removed: .

8.23 — Weyl’s Formula

Derive .

8.24 — Electrostatics of a Cosmic String

A cosmic string reduces the angular range to where .

8.25 — Complex Potential for a Line Array

Show is the complex potential for alternating line charges at and .